Although entropy is all about chaos and disorder, our entropy calculator is here to answer all your entropy related questions in a simple and organized way. In the following text, we will give an entropy definition, as well as a couple of ways of calculating entropy change. We'll explain the Gibbs free energy equation, the change in entropy formula for chemical reactions, and the isothermal process for ideal gases.
Have you ever heard someone saying that the universe tends toward chaos? Well, let's dive in that statement and find out what it means!
Entropy - definition
The second law of thermodynamics states that:
The disorder of a system is always increasing.
Entropy is the measure of that disorder. But why measure disorder, and is it even possible? Physically, we can't measure entropy, but we can calculate it. It's one of the main determinants of the spontaneity of a reaction.
A spontaneous process is one that doesn't require an outside source of energy to proceed. It doesn't have to be a fast - it can even be still occurring when the heat death of the universe occurs - but if it would proceed without the addition of any outside energy, it's spontaneous.
It might sound complicated, but you'll understand it easily with an everyday example. Let's say you've made yourself a hot cup of coffee. You add some milk to it. You observed that the milk quickly mixes with the coffee. You intuitively know that the opposite process is not possible - the milk won't separate from coffee by itself.
Any spontaneous process increases the disorder of the universe. As stated by a physicist Rudolf Clausius: "The entropy of the universe tends to a maximum."
The entropy of a system is strictly connected to the systems energy. Every system tends toward stability, and, for an irreversible process, maximum stability is reached it when the system's energy is most disordered.
How to calculate entropy change?
Entropy is a state function. This means that it is dependent on the entropies of the initial and final states of a system, not on the path the system takes. In chemistry, it's the difference between the entropy of the products and the reactants.
For chemical reactions, the change in entropy formula is:
ΔSreaction = ΔSproducts - ΔSreactants
Entropy (S) is normally measured in J/K, but standard entropy (So) is also used. This value is measured at 298.15 K and at a pressure of 1 bar. Its units are J/K*mol. The above equation can also be written in a standard entropy form:
ΔSoreaction = ΔSoproducts - ΔSoreactants
Let's look at some standard entropy values:
As you see, gases have higher entropy than liquids and solids. It's because of the random movement of the molecules. On the other hand, diamond, a highly ordered solid, has entropy very close to zero.
Gibbs free energy equation
What is Gibbs free energy? It's the energy in a system available to do work on its surroundings at constant pressure and temperature. It's a function of both enthalpy and entropy, and is used to predict the spontaneity of a processes. The Gibbs free energy equation is:
ΔG = ΔH - (T * ΔS),
ΔGis the change in Gibbs free energy.
ΔHis the change in enthalpy.
Tis the temperature (in Kelvin).
ΔSis the change in entropy.
Earlier, we talked about spontaneity of a process and how it is associated with entropy. We can also define it with regards to the change in free energy:
ΔG<0- a spontaneous process (a round boulder rolling down a hill).
ΔG=0- a system at equilibrium (a round boulder placed on a flat surface).
ΔG>0- a nonspontaneous process - additional energy must put in for the reaction to happen (a round boulder being pushed up a hill).
The direction of a free energy change can be either enthalpy- or entropy-driven. If:
ΔH >> T * ΔSthen the reaction is enthalpy-driven. The free energy comes mostly from a flow of thermal energy.
ΔH << T * ΔSthen the reaction is entropy-driven. The increase of disorder provides most of the free energy.
Change in entropy formula - the isothermal process of an ideal gas
For the isothermal process of an ideal gas, entropy can be a function of both volume and pressure:
ΔS = n * R * ln(V2/V1) = - n * R * ln(P2/P1), where
nis the number of moles.
Ris the gas constant, 8.3145 J/mol*K.
V2,V1is the final and initial volume.
P2,P1is the final and initial pressure.
Isothermal processes are those that occur at a constant temperature. You might have met the base equation for a change in entropy in these conditions before:
ΔS = ΔQ / T. In the equation above, we switched the change of heat (ΔQ) for values that will make calculations easier for you.
When you heat up a gas in a closed container, you give the molecules additional energy. Now the molecules have more ways of spreading energy than before, so increasing temperature increases entropy.
If there is a chemical reaction that involves an increase in the number of gas molecules, entropy will rise.
Substances with a simpler atomic structure will have lower entropy than more complex ones.
Have you enjoyed our entropy calculator? Would you like to know how entropy is used in statistics? Check out the Shannon entropy calculator next!